Electronic structures of bent lanthanide(III) complexes with two N-donor ligands.

ABSTRACT: Low coordinate metal complexes can exhibit superlative physicochemical properties, but this chemistry is challenging for the lanthanides (Ln) due to their tendency to maximize electrostatic contacts in predominantly ionic bonding regimes. Although a handful of Ln²⁺ complexes with only two monodentate ligands have been isolated, examples in the most common +3 oxidation state have remained elusive due to the greater electrostatic forces of Ln³⁺ ions. Here, we report bent Ln³⁺ complexes with two bis(silyl)amide ligands; in the solid state the Yb³⁺ analogue exhibits a crystal field similar to its three coordinate precursor rather than that expected for an axial system. This unanticipated finding is in opposition to the predicted electronic structure

SUBMITTER: Nicholas HM 

PROVIDER: S-EPMC7020784 | biostudies-literature | 2019 Dec

REPOSITORIES: biostudies-literature