Light-regulated growth from dynamic swollen substrates for making rough surfaces.
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ABSTRACT: Natural organic structures form via a growth mode in which nutrients are absorbed, transported, and integrated. In contrast, synthetic architectures are constructed through fundamentally different methods, such as assembling, molding, cutting, and printing. Here, we report a photoinduced strategy for regulating the localized growth of microstructures from the surface of a swollen dynamic substrate, by coupling photolysis, photopolymerization, and transesterification together. Photolysis is used to generate dissociable ionic groups to enhance the swelling ability that drives nutrient solutions containing polymerizable components into the irradiated region, photopolymerization converts polymerizable components into polymers, and transesterification incorporates newly formed polymers into the
SUBMITTER: Xue L
PROVIDER: S-EPMC7031321 | biostudies-literature | 2020 Feb
REPOSITORIES: biostudies-literature
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