Isothermal Kinetics of Poly(butylene adipate-co-butylene itaconate) Copolyesters with Ethylenediaminetetraacetic Acid.

ABSTRACT: A series of aliphatic copolyesters, poly(butylene adipate-co-butylene itaconate) (PBABI), have been synthesized using melt polycondensation of adipic acid (AA), itaconic acid (IA), 1,4-butanediol (1,4-BDO), and the tetra-functional group of ethylenediaminetetraacetic acid (EDTA, 0.1 mol %) to form partially cross-linking density as novel thermoplastic unsaturated copolyesters in our previous research. The crystal phase of PBABI copolyesters tended to prefer thermodynamics in the presence of a small amount of EDTA. The isothermal crystallization analysis revealed that the PBABI with EDTA exhibited a higher crystallization rate and a shorter half-time of crystallization than neat PBABI copolyesters. All of the sizes of spherulite/sheet crystals in the BA/BI = 9/1 are smaller than at BA/BI =

SUBMITTER: Chen CW 

PROVIDER: S-EPMC7033981 | biostudies-literature | 2020 Feb

REPOSITORIES: biostudies-literature