Anisotropic viscoelastic phase separation in polydisperse hard rods leads to nonsticky gelation.

ABSTRACT: Spinodal demixing into two phases having very different viscosities leads to viscoelastic networks-i.e., gels-usually as a result of attractive particle interactions. Here, however, we demonstrate demixing in a colloidal system of polydisperse, rod-like clay particles that is driven by particle repulsions instead. One of the phases is a nematic liquid crystal with a highly anisotropic viscosity, allowing flow along the director, but suppressing it in other directions. This phase coexists with a dilute isotropic phase. Real-space analysis and molecular-dynamics simulations both reveal a long-lived network structure that is locally anisotropic, yet macroscopically isotropic. We show that our system exhibits the characteristics of colloidal gelation, leading to nonsticky gels.

SUBMITTER: Ferreiro-Cordova C 

PROVIDER: S-EPMC7035602 | biostudies-literature | 2020 Feb

REPOSITORIES: biostudies-literature