Neutron Total Scattering Studies of Group II Titanates (ATiO₃, A²⁺ = Mg, Ca, Sr, Ba).

ABSTRACT: Neutron total scattering measurements were conducted on MgTiO₃, CaTiO₃, SrTiO₃, and BaTiO₃ to simultaneously investigate the local and average structure of these materials. The local structures of MgTiO₃, CaTiO₃, and SrTiO₃ were well modelled using the refined average structural models: trigonal R[Formula: see text], orthorhombic Pbnm, and cubic Pm[Formula: see text]m respectively. However the local structure for BaTiO₃, at both temperatures where the average structure is orthorhombic Amm2 and tetragonal P4mm, was best described by the rhombohedral R3m model. Only the R3m model was able to account for the observed displacement of titanium in the [111] direction. Furthermore, box-car type refinements wer

SUBMITTER: Culbertson CM 

PROVIDER: S-EPMC7048731 | biostudies-literature | 2020 Feb

REPOSITORIES: biostudies-literature