Molecularly tunable thin-film nanocomposite membranes with enhanced molecular sieving for organic solvent forward osmosis.

ABSTRACT: Thin-film nanocomposites (TFN) functionalized with tunable molecular-sieving nanomaterials have been employed to tailor membranes, with an enhanced permeability and selectivity. Herein, water-soluble hollow cup-like macrocyclic molecules, sulfothiacalix[4]arene (STCAss) and sulfocalix[4]arene (SCA), are ionically bonded into the polyamide network to engineer the molecular-sieving properties of TFN membranes for organic solvent forward osmosis (OSFO). Introducing both STCAss and SCA into the polyamide network not only increases the free volume, but also reduces the thickness of the TFN layers. Combining with their molecularly tunable size of the lower cavities, both STCAss and SCA enable the TFN membranes to size exclusively reject the draw solutes, but only STCAss-functionalized membrane h

SUBMITTER: Li B 

PROVIDER: S-EPMC7057969 | biostudies-literature | 2020 Mar

REPOSITORIES: biostudies-literature