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Titanium-Catalyzed Hydroaminoalkylation of Ethylene.

ABSTRACT: The first examples of titanium-catalyzed hydroaminoalkylation reactions of ethylene with secondary amines are presented. The reactions can be achieved with various titanium catalysts and they do not require the use of high pressure equipment. In addition, the first solid-state structure of a titanapyrrolidine that is formed by insertion of an alkene into the Ti-C bond of a titanaaziridine is reported.

SUBMITTER: Rosien M

PROVIDER: S-EPMC7064915 | biostudies-literature | 2020 Feb

REPOSITORIES: biostudies-literature

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Titanium-Catalyzed Hydroaminoalkylation of Ethylene.

Rosien Michael M Töben Iris I Schmidtmann Marc M Beckhaus Rüdiger R Doye Sven S

Chemistry (Weinheim an der Bergstrasse, Germany) 20200120 10

The first examples of titanium-catalyzed hydroaminoalkylation reactions of ethylene with secondary amines are presented. The reactions can be achieved with various titanium catalysts and they do not require the use of high pressure equipment. In addition, the first solid-state structure of a titanapyrrolidine that is formed by insertion of an alkene into the Ti-C bond of a titanaaziridine is reported. ...[more]

PMID: 31799706

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