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Iron-Catalyzed Oxidative C-C Cross-Coupling Reaction of Tertiary Anilines with Hydroxyarenes by Using Air as Sole Oxidant.

ABSTRACT: A mild procedure for the oxidative C-C cross-coupling of tertiary anilines with phenols is described which provides the products generally in high yields and with excellent selectivity. The reaction is catalyzed by the hexadecafluorinated iron-phthalocyanine complex FePcF₁₆ in the presence of substoichiometric amounts of methanesulfonic acid and ambient air as sole oxidant.

SUBMITTER: Purtsas A

PROVIDER: S-EPMC7064917 | biostudies-literature | 2020 Feb

REPOSITORIES: biostudies-literature

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Iron-Catalyzed Oxidative C-C Cross-Coupling Reaction of Tertiary Anilines with Hydroxyarenes by Using Air as Sole Oxidant.

Purtsas Alexander A Kataeva Olga O Knölker Hans-Joachim HJ

Chemistry (Weinheim an der Bergstrasse, Germany) 20200204 11

A mild procedure for the oxidative C-C cross-coupling of tertiary anilines with phenols is described which provides the products generally in high yields and with excellent selectivity. The reaction is catalyzed by the hexadecafluorinated iron-phthalocyanine complex FePcF<sub>16</sub> in the presence of substoichiometric amounts of methanesulfonic acid and ambient air as sole oxidant. ...[more]

PMID: 31858652

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