Impact of Polymer Backbone Fluorination on the Charge Generation/Recombination Patterns and Vertical Phase Segregation in Bulk Heterojunction Organic Solar Cells.

ABSTRACT: Incorporating fluorine (-F) substituents along the main-chains of polymer donors and acceptors is an effective strategy toward efficient bulk-heterojunction (BHJ) solar cells. Specifically, F-substituted polymers often exhibit planar conformations, leading to favorable packing, and electronic coupling. However, the effects of fluorine substituents on the charge generation and recombination characteristics that determine the overall efficiency of BHJ active layers remain critically important issues to examine. In this report, two PBDT[2X]T polymer analogs -poly[4,8-bis((2-ethylhexyl)oxy)benzo[1,2-b:4, 5-b']dithiophene-thiophene] [PBDT[2H]T] and its F-substituted counterpart poly[4,8-bis((2-ethylhexyl)oxy)benzo[1,2-b:4,5-b']dithiophene-3,4-difluoro-thiophene] [PBDT[2F]T]-are studied to syste

SUBMITTER: Shao Y 

PROVIDER: S-EPMC7066253 | biostudies-literature | 2020

REPOSITORIES: biostudies-literature