Epitaxial nucleation and lateral growth of high-crystalline black phosphorus films on silicon.

ABSTRACT: Black phosphorus (BP) is a promising two-dimensional layered semiconductor material for next-generation electronics and optoelectronics, with a thickness-dependent tunable direct bandgap and high carrier mobility. Though great research advantages have been achieved on BP, lateral synthesis of high quality BP films still remains a great challenge. Here, we report the direct growth of large-scale crystalline BP films on insulating silicon substrates by a gas-phase growth strategy with an epitaxial nucleation design and a further lateral growth control. The optimized lateral size of the achieved BP films can reach up to millimeters, with the ability to modulate thickness from a few to hundreds of nanometers. The as-grown BP films exhibit excellent electrical properties, with a field-effect an

SUBMITTER: Xu Y 

PROVIDER: S-EPMC7067838 | biostudies-literature | 2020 Mar

REPOSITORIES: biostudies-literature