Reduction of a dihydroboryl cation to a boryl anion and its air-stable, neutral hydroboryl radical through hydrogen shuttling.

ABSTRACT: The addition of Lewis bases to a cyclic (alkyl)(amino)carbene (CAAC)-supported dihydroboron triflate yields the mixed doubly base-stabilised dihydroboryl cations [(CAAC)BH₂L]⁺. Of these, [(CAAC)₂BH₂]OTf (OTf = triflate) underwent facile two-electron reduction with KC₈ owing to a 1,2-hydride migration from boron to the carbene carbon to yield a stable hydroboryl anion. One-electron oxidation of the latter yielded the first neutral hydroboryl radical, which is bench-stable in the solid state.

SUBMITTER: Hagspiel S 

PROVIDER: S-EPMC7069503 | biostudies-literature | 2020 Jan

REPOSITORIES: biostudies-literature