Single-Chain Magnet Based on Cobalt(II) Thiocyanate as XXZ Spin Chain.

ABSTRACT: The cobalt(II) in [Co(NCS)₂ (4-methoxypyridine)₂ ]_n are linked by pairs of thiocyanate anions into linear chains. In contrast to a previous structure determination, two crystallographically independent cobalt(II) centers have been found to be present. In the antiferromagnetic state, below the critical temperature (T_c =3.94 K) and critical field (H_c =290 Oe), slow relaxations of the ferromagnetic chains are observed. They originate mainly from defects in the magnetic structure, which has been elucidated by micromagnetic Monte Carlo simulations and ac measurements using pristine and defect samples. The energy barriers of the relaxations are Δ_τ1 =44.9(5) K and Δ_τ2 =26.0(7) K for long and short spin chains, respective

SUBMITTER: Rams M 

PROVIDER: S-EPMC7078958 | biostudies-literature | 2020 Mar

REPOSITORIES: biostudies-literature