Direct observation of nuclear reorganization driven by ultrafast spin transitions.

ABSTRACT: One of the most basic molecular photophysical processes is that of spin transitions and intersystem crossing between excited states surfaces. The change in spin states affects the spatial distribution of electron density through the spin orbit coupling interaction. The subsequent nuclear reorganization reports on the full extent of the spin induced change in electron distribution, which can be treated similarly to intramolecular charge transfer with effective reaction coordinates depicting the spin transition. Here, single-crystal [Fe^II(bpy)₃](PF₆)₂, a prototypical system for spin crossover (SCO) dynamics, is studied using ultrafast electron diffraction in the single-photon excitation regime. The photoinduced SCO dynamics are resolved, revealing

SUBMITTER: Jiang Y 

PROVIDER: S-EPMC7090058 | biostudies-literature | 2020 Mar

REPOSITORIES: biostudies-literature