Measurement of Solvation Ability of Solvents by Porphyrin-Based Solvation/Desolvation Indicators.

ABSTRACT: A new solvent scale, solvation ability (SA), was developed to arrange solvents in the order of their SA for large π-conjugated compounds. The SA of a solvent was determined in a binary solvent system of an assessed solvent and a standard "good" solvent (GS) or "poor" solvent (PS), chloroform or methylcyclohexane, respectively, in the presence of two types of solvation/desolvation indicators, 1Zn₂ and 2Zn₂ . The latter comprises bis(imidazolylporphyrinatozinc) linked via a 1,3-butadiynylene moiety having linear alkyl and hydrophilic side chains, respectively. GSs and PSs give extended (E-) and stacked (S-) supramolecular polymers of the indicators, respectively. SA values are defined as vol % of the standard solvent added to an assessed solvent to give th

SUBMITTER: Sugimoto M 

PROVIDER: S-EPMC7098040 | biostudies-literature | 2020 Mar

REPOSITORIES: biostudies-literature