Photovoltaic activity of electrodes based on intact photosystem I electrodeposited on bare conducting glass.

ABSTRACT: We demonstrate photovoltaic activity of electrodes composed of fluorine-doped tin oxide (FTO) conducting glass and a multilayer of trimeric photosystem I (PSI) from cyanobacterium Synechocystis sp. PCC 6803 yielding, at open circuit potential (OCP) of + 100 mV (vs. SHE), internal quantum efficiency of (0.37 ± 0.11)% and photocurrent density of up to (0.5 ± 0.1) µA/cm². The photocurrent measured for OCP is of cathodic nature meaning that preferentially the electrons are injected from the conducting layer of the FTO glass to the photooxidized PSI primary electron donor, P700⁺, and further transferred from the photoreduced final electron acceptor of PSI, F_b^-, via ascorbate electrolyte to the counter electrode. This observation is consistent with pre

SUBMITTER: Szewczyk S 

PROVIDER: S-EPMC7113217 | biostudies-literature | 2020 Apr

REPOSITORIES: biostudies-literature