Aerobic synthesis of N-sulfonylamidines mediated by N-heterocyclic carbene copper(I) catalysts.

ABSTRACT: A new catalytic strategy for the one-pot synthesis of N-sulfonylamidines is described. The cationic copper(I) complexes were found to be highly active and efficient under mild conditions in air and in the absence of solvent. A copper acetylide is proposed as key intermediate in this transformation.

SUBMITTER: Lazreg F 

PROVIDER: S-EPMC7113546 | biostudies-literature | 2020

REPOSITORIES: biostudies-literature