Redox activity of a dissymmetric ligand bridging divalent ytter-bium and reactive nickel fragments.

ABSTRACT: The reaction of a reactive nickel dimethyl 1 bearing a redox-active, dissymmetric ligand, which is obtained by deprotonation of 2-pyrimidin-2-yl-1H-benzimidazole (Hbimpm) with a divalent lanthanide complex, Cp*₂Yb(OEt₂), affords an unprecedented, trimeric 2 with C(sp³)-C(sp³) bond formation between two ligands in an exo position. Meanwhile, the transient, dimeric species 3 can be isolated with the same ligand coupling fashion, however, with a drastic distorsion angle of the bimpm ligand and reactive NiMe₂ fragment, revealing the possible mechanism of this rearrangement. A much more stable dimeric congener, 5, with an exo ligand coupling, is synthesized in the presence of 18-crown-6, which captures the potass

SUBMITTER: Wang D 

PROVIDER: S-EPMC7116723 | biostudies-literature | 2021 Feb

REPOSITORIES: biostudies-literature