Nickel(II) Nanoparticles Immobilized on EDTA-Modified Fe3O4@SiO2 Nanospheres as Efficient and Recyclable Catalysts for Ligand-Free Suzuki-Miyaura Coupling of Aryl Carbamates and Sulfamates.

ABSTRACT: A highly efficient and air-, thermal-, and moisture-stable nickel-based catalyst with excellent magnetic properties supported on silica-coated magnetic Fe3O4 nanoparticles was successfully synthesized. It was well characterized by Fourier transform infrared spectroscopy, powder X-ray diffraction, transmission electron microscopy, field emission scanning electron microscopy, thermogravimetric analysis, dynamic light scattering (DLS), X-ray photoelectron spectroscopy, vibration sample magnetometry, energy-dispersive X-ray analysis, inductively coupled plasma analysis, and nitrogen adsorption-desorption isotherm analysis. The Suzuki-Miyaura coupling reaction between aryl carbamates and/or sulfamates with arylboronic acids was selected to demonstrate the catalytic activity and efficiency of th

SUBMITTER: Dindarloo Inaloo I 

PROVIDER: S-EPMC7144170 | biostudies-literature | 2020 Apr

REPOSITORIES: biostudies-literature