Pure Acetylene Semihydrogenation over Ni-Cu Bimetallic Catalysts: Effect of the Cu/Ni Ratio on Catalytic Performance.

ABSTRACT: Ethylene is an important chemical raw material and with the increasing consumption of petroleum resources, the production of ethylene through the calcium carbide acetylene route has important research significance. In this work, a series of bimetallic catalysts with different Cu/Ni molar ratios are prepared by co-impregnation method for the hydrogenation of calcium carbide acetylene to ethylene. The introduction of an appropriate amount of Cu effectively inhibits not only the formation of ethane and green oil, thus increasing the selectivity of ethylene, but also the formation of carbon deposits, which improves the stability of the catalyst. The ethylene selectivity of the Ni-Cu bimetallic catalyst increases from 45% to 63% compared with the Ni monometallic counterpart and the acetylene co

SUBMITTER: Zhou S 

PROVIDER: S-EPMC7153591 | biostudies-literature | 2020 Mar

REPOSITORIES: biostudies-literature