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Alternative Preparation of Improved NiMo-Alumina Deoxygenation Catalysts.


ABSTRACT: This investigation deals with NiMo-alumina hydrotreating catalysts effective in the deoxygenation of rapeseed oil. The main goal was to compare catalyst structure and their deoxygenation performance and to link these parameters to reveal important structural information regarding the catalyst's intended use. Catalysts were prepared from different precursors (nickel acetate tetrahydrate/molybdenyl acetylacetonate in ethanol and water vs. nickel nitrate hexahydrate/ammonium heptamolybdate tetrahydrate in water), which resulted in their contrasting structural arrangement. These changes were characterized by elemental composition determination, UV-Vis diffuse reflectance spectroscopy, temperature programmed reduction by hydrogen, nitrogen physisorption at 77 K, scanning and transmission electr

SUBMITTER: Priecel P 

PROVIDER: S-EPMC7157445 | biostudies-literature | 2020

REPOSITORIES: biostudies-literature