A Stable Calcium Alumanyl.

ABSTRACT: A seven-membered N,N'-heterocyclic potassium alumanyl nucleophile is introduced and utilised in the metathetical synthesis of Mg-Al and Ca-Al bonded derivatives. Both species have been characterised by experimental and theoretical means, allowing a rationalisation of the greater reactivity of the heavier group 2 species implied by an initial assay of their reactivity.

SUBMITTER: Schwamm RJ 

PROVIDER: S-EPMC7159353 | biostudies-literature | 2020 Mar

REPOSITORIES: biostudies-literature