Concise Synthesis of Linderaspirone A and Bi-linderone.
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ABSTRACT: Photogenic: The synthesis of linderaspirone A has been accomplished in only three steps by a Darzens cyclopentenedione synthesis and dioxygen-assisted photochemical dimerization. Moreover, the thermal isomerization of linderaspirone A into bi-linderone has been discovered, which may give clues to the biosynthetic pathway for bi-linderone.
SUBMITTER: Xiao F
PROVIDER: S-EPMC7159600 | biostudies-literature | 2013 Mar
REPOSITORIES: biostudies-literature
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