Characterization of the ALSEP Process at Equilibrium: Speciation and Stoichiometry of the Extracted Complex.

ABSTRACT: We have determined the identity of the complexes extracted into the ALSEP process solvent from solutions of nitric acid. The ALSEP process is a new solvent extraction separation designed to separate americium and curium from trivalent lanthanides in irradiated nuclear fuel. ALSEP employs a mixture of two extractants, 2-ethylhexyl phosphonic acid mono-2-ethylhexyl ester (HEH[EHP]) and N,N,N',N'-tetra(2-ethylhexyl)diglycolamide (TEHDGA) in n-dodecane, which makes it difficult to ascertain the nature of the extracted metal complexes. It is often asserted that the weak acid extractant HEH[EHP] does not participate in the extracted complex under ALSEP extraction conditions (2-4 M HNO₃). However, the analysis of the Am extraction equilibria, Nd absor

SUBMITTER: Picayo GA 

PROVIDER: S-EPMC7161052 | biostudies-literature | 2020 Apr

REPOSITORIES: biostudies-literature