Study on the Magneto-Structural Correlation of a New Dinuclear Cobalt(II) Complex with Double μ-Phenoxo Bridges.

ABSTRACT: A new μ-phenoxo-bridged dinuclear cobalt(II) complex, [Co₂(L)₂(acac)₂(H₂O)] (1), has been synthesized by employing a new ligand, (4-methyl-2-formyl-6-(((2-trifluoromethyl)phenyl)methyliminomethyl) phenol) (HL). Structural analysis of complex 1 reveals that the geometry around cobalt centers is best described as a distorted octahedron and the distance of cobalt neighbors is 3.128(0) Å. The magnetic property studies indicate that complex 1 exhibits strong spin-orbit coupling effects and weak ferromagnetic coupling between two high-spin Co(II) centers linked by double μ-O_phenoxo bridges, with J = 1.87(2) cm^-1. The studies show that not only the Co-O-Co angle affects the alignment of the cobalt spins

SUBMITTER: Song XJ 

PROVIDER: S-EPMC7161063 | biostudies-literature | 2020 Apr

REPOSITORIES: biostudies-literature