Model Protective Films on Cu-Zn Alloys Simulating the Inner Surfaces of Historical Brass Wind Instruments by EIS and XPS.

ABSTRACT: The present work focuses on the characterization of brass surfaces after contact with artificial saliva solution at pH 7.4 and phosphate buffer solution at pH 7 simulating two extreme conditions that might occur when playing ancient brass wind instruments in the context of historically informed performance practice. The composition and the morphology of the film formed following the contact with the solutions for 1, 3, and 16 h were investigated by ex situ X-ray photoelectron spectroscopy (XPS) and scanning electron microscopy (SEM) to shed a light on the surface changes upon time. In situ electrochemical impedance spectroscopy (EIS) was used to study the mechanism of corrosion and protection of the alloys. The results could be interpreted using a reliable equivalent electrical circuit; th

SUBMITTER: Fantauzzi M 

PROVIDER: S-EPMC7174669 | biostudies-literature | 2020

REPOSITORIES: biostudies-literature