Ontology highlight
ABSTRACT:
SUBMITTER: Yakiyama Y
PROVIDER: S-EPMC7176931 | biostudies-literature | 2020
REPOSITORIES: biostudies-literature
Yakiyama Yumi Y Hishikawa Shota S Sakurai Hidehiro H
Beilstein journal of organic chemistry 20200415
Buckybowls bearing a C<sub>70</sub> fragment having two alkoxy groups were synthesized and their structural and optical properties were investigated by single crystal X-ray analysis and UV-vis spectroscopy. In the synthesis of dioxole derivative <b>5b</b>, the regioisomer <b>5c</b> was also produced. The yield of <b>5c</b> was increased by increasing the reaction temperature, indicating that the rearrangement might involve the equilibrium between the Pd(IV) intermediates through C-H bond activat ...[more]