Unknown

Dataset Information

0

Synthesis of C70-fragment buckybowls bearing alkoxy substituents.


ABSTRACT: Buckybowls bearing a C70 fragment having two alkoxy groups were synthesized and their structural and optical properties were investigated by single crystal X-ray analysis and UV-vis spectroscopy. In the synthesis of dioxole derivative 5b, the regioisomer 5c was also produced. The yield of 5c was increased by increasing the reaction temperature, indicating that the rearrangement might involve the equilibrium between the Pd(IV) intermediates through C-H bond activation.

SUBMITTER: Yakiyama Y 

PROVIDER: S-EPMC7176931 | biostudies-literature | 2020

REPOSITORIES: biostudies-literature

altmetric image

Publications

Synthesis of C<sub>70</sub>-fragment buckybowls bearing alkoxy substituents.

Yakiyama Yumi Y   Hishikawa Shota S   Sakurai Hidehiro H  

Beilstein journal of organic chemistry 20200415


Buckybowls bearing a C<sub>70</sub> fragment having two alkoxy groups were synthesized and their structural and optical properties were investigated by single crystal X-ray analysis and UV-vis spectroscopy. In the synthesis of dioxole derivative <b>5b</b>, the regioisomer <b>5c</b> was also produced. The yield of <b>5c</b> was increased by increasing the reaction temperature, indicating that the rearrangement might involve the equilibrium between the Pd(IV) intermediates through C-H bond activat  ...[more]

Similar Datasets

| S-EPMC9059989 | biostudies-literature
| S-EPMC9511991 | biostudies-literature
| S-EPMC4546508 | biostudies-literature
| S-EPMC11436105 | biostudies-literature
| S-EPMC2496920 | biostudies-literature
| S-EPMC7400669 | biostudies-literature
| S-EPMC11890062 | biostudies-literature
| S-EPMC10681718 | biostudies-literature
| S-EPMC10419492 | biostudies-literature
| S-EPMC9099540 | biostudies-literature