Ascertaining Hydrogen-Abstraction Reaction Efficiencies of Halogenated Organic Compounds in Electron Impact Ionization Processes by Gas Chromatography-High-Resolution Mass Spectrometry.

ABSTRACT: H-Abstraction reactions occurring during electron impact ionization processes in electron ionization mass spectrometry (EI-MS) are a long-standing and crucial topic in MS research. Yet, some critical relevant mechanisms are controversial and ambiguous, and information about the EI-induced H-abstraction reactions of halogenated organic compounds (HOCs) is completely in the dark. This study provides a systematic investigation of H-abstraction reactions of HOCs taking place in the EI source using ¹³C₆-hexachlorobenzene (¹³C₆-HCB) and ¹³C₆-hexabromobenzene (¹³C₆-HBB) as exemplary compounds by gas chromatography (GC)-high-resolution mass spectrometry (GC-HRMS). The H-abstraction efficiencies were evaluated w

SUBMITTER: Tang C 

PROVIDER: S-EPMC7178364 | biostudies-literature | 2020 Apr

REPOSITORIES: biostudies-literature