The Different Effects of Organic Amines on Synthetic Metal Phosphites/Phosphates.

ABSTRACT: Four metal phosphites/phosphates crystal materials C₈N₄H₃₄Al₂P₄O₁₈ (1), C₃N₂H₁₇GaP₂O₈ (2), H₅In₂P₃O₁₀ (3), and H₉In₂P₃O₁₃ (4) have been solvothermally synthesized by organic amines in the presence of mixed solvents. Structural analyses indicate that compound 1 and 2 show one-dimensional (1D) chain structures; compound 3 and 4 are three-dimensional (3D) inorganic open-framework indium phosphites. Organic amines show different mechanisms in the four compounds. The 2,2'-bipyridine organic amine acts as a template source and it breaks down small molecules, which enter into the structure o

SUBMITTER: Wang X 

PROVIDER: S-EPMC7178704 | biostudies-literature | 2020 Apr

REPOSITORIES: biostudies-literature