The Dynamic Nature of CO Adlayers on Pt(111) Electrodes.

ABSTRACT: CO adlayers on Pt(111) electrode surfaces are an important electrochemical system and of great relevance to electrocatalysis. The potential-dependent structure and dynamics of these adlayers are complex and still controversial, especially in the CO pre-oxidation regime. We here employ in situ high-speed scanning tunneling microscopy for studying the surface phase behavior in CO-saturated 0.1 m H2 SO4 on the millisecond time scale. At potentials near the onset of CO pre-oxidation local fluctuations in the (2×2)-CO adlayer are observed, which increase towards more positive potentials. Above 0.20 V (vs. Ag/AgCl), this leads to an adlayer where COad apparently reside on every top site, but still exhibit a (2×2) superstructure modulation. We interpret this observation as a dynamic effect, cause

SUBMITTER: Wei J 

PROVIDER: S-EPMC7187359 | biostudies-literature | 2020 Apr

REPOSITORIES: biostudies-literature