Operando visualisation of battery chemistry in a sodium-ion battery by ²³Na magnetic resonance imaging.

ABSTRACT: Sodium-ion batteries are a promising battery technology for their cost and sustainability. This has led to increasing interest in the development of new sodium-ion batteries and new analytical methods to non-invasively, directly visualise battery chemistry. Here we report operando ¹H and ²³Na nuclear magnetic resonance spectroscopy and imaging experiments to observe the speciation and distribution of sodium in the electrode and electrolyte during sodiation and desodiation of hard carbon in a sodium metal cell and a sodium-ion full-cell configuration. The evolution of the hard carbon sodiation and subsequent formation and evolution of sodium dendrites, upon over-sodiation of the hard carbon, are observed and mapped by ²³Na nuclear magnetic resonance spectros

SUBMITTER: Bray JM 

PROVIDER: S-EPMC7190614 | biostudies-literature | 2020 Apr

REPOSITORIES: biostudies-literature