Application and Properties of Microporous Carbons Activated by ZnCl₂: Adsorption Behavior and Activation Mechanism.

ABSTRACT: Herein, polypyrrole-based porous carbon (PPC) was prepared by ZnCl₂ activation for toluene adsorption from paraffin liquid. The structure properties were adjusted by a dosage of activating agents and carbonization temperature. The result with a 3:1 mass ratio of ZnCl₂/PPy at 600 °C showed the highest micropore area and percentage of micropore volume of 1105 m²/g and 86.26%, respectively. In addition, the PPC surface was rich in functional groups and obtained a high N-doped content from 7.00 to 8.82%. The toluene adsorption behavior onto the PPC was comprehensively investigated including isotherms, kinetics, and thermodynamics. The adsorption isotherm accorded with the Freundlich model well, and the kinetic model was fitted more closely to the pseudo-second-

SUBMITTER: Li B 

PROVIDER: S-EPMC7191858 | biostudies-literature | 2020 Apr

REPOSITORIES: biostudies-literature