Iridium Corroles Exhibit Weak Near-Infrared Phosphorescence but Efficiently Sensitize Singlet Oxygen Formation.

ABSTRACT: Six-coordinate iridium(III) triarylcorrole derivatives, Ir[TpXPC)]L₂, where TpXPC = tris(para-X-phenyl)corrole (X = CF₃, H, Me, and OCH₃) and L = pyridine (py), trimethylamine (tma), isoquinoline (isoq), 4-dimethylaminopyridine (dmap), and 4-picolinic acid (4pa), have been examined, with a view to identifying axial ligands most conducive to near-infrared phosphorescence. Disappointingly, the phosphorescence quantum yield invariably turned out to be very low, about 0.02 - 0.04% at ambient temperature, with about a two-fold increase at 77 K. Phosphorescence decay times were found to be around ~5 µs at 295 K and ~10 µs at 77 K. Fortunately, two of the Ir[TpCF₃PC)]L₂ derivatives, which were tested for their ability to sensitize singlet oxy

SUBMITTER: Thomassen IK 

PROVIDER: S-EPMC7200656 | biostudies-literature | 2020 May

REPOSITORIES: biostudies-literature