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Novel approach for effective removal of methylene blue dye from water using fava bean peel waste.

ABSTRACT: Fava bean peels, Vicia faba (FBP) are investigated as biosorbents for the removal of Methylene Blue (MB) dye from aqueous solutions through a novel and efficient sorption process utilizing ultrasonic-assisted (US) shaking. Ultrasonication remarkably enhanced sorption rate relative to conventional (CV) shaking, while maintaining the same sorption capacity. Ultrasonic sorption rate amounted to four times higher than its conventional counterpart at 3.6 mg/L initial dye concentration, 5 g/L adsorbent dose, and pH 5.8. Under the same adsorbent dose and pH conditions, percent removal ranged between 70-80% at the low dye concentration range (3.6-25 mg/L) and reached about 90% at 50 mg/L of the initial dye concentration. According to the Langmuir model, maximum sorption capacity was estimated to be 140 mg/g. A multiple linear regression statistical model revealed that adsorption was significantly affected by initial concentration, adsorbent dose and time. FBP could be successfully utilized as a low-cost biosorbent for the removal of MB from wastewater via US biosorption as an alternative to CV sorption. US biosorption yields the same sorption capacities as CV biosorption, but with significant reduction in operational times.

SUBMITTER: Bayomie OS

PROVIDER: S-EPMC7210991 | biostudies-literature | 2020 May

REPOSITORIES: biostudies-literature

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Novel approach for effective removal of methylene blue dye from water using fava bean peel waste.

Bayomie Omar S OS Kandeel Haitham H Shoeib Tamer T Yang Hu H Youssef Noha N El-Sayed Mayyada M H MMH

Scientific reports 20200508 1

Fava bean peels, Vicia faba (FBP) are investigated as biosorbents for the removal of Methylene Blue (MB) dye from aqueous solutions through a novel and efficient sorption process utilizing ultrasonic-assisted (US) shaking. Ultrasonication remarkably enhanced sorption rate relative to conventional (CV) shaking, while maintaining the same sorption capacity. Ultrasonic sorption rate amounted to four times higher than its conventional counterpart at 3.6 mg/L initial dye concentration, 5 g/L adsorben ...[more]

PMID: 32385345

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Project description:The ongoing discharge of hazardous dyes from industrial processes has intensified global water pollution, posing serious threats to aquatic ecosystems and human health. Addressing this challenge, our study explores the potential of bio-based carbon nanomaterials (CNM), synthesized from onion peel biowaste and designated as ON11, as effective agents in dye removal. These CNMs were incorporated into a mixed matrix membrane (MMM), using polysulfone (PSU) as the membrane substrate, to enhance dye adsorption. The CNM synthesis was achieved through a simple, eco-friendly process. We examined their impact on adsorption efficiency by introducing ON11 nanoparticles at varying concentrations into the PSU membrane (ON11@PSU). This CNM-embedded membrane structure offers a solution to challenges associated with the large-scale application of nanomaterials, particularly by minimizing leaching into water and improving durability. The ON11 and ON11@PSU membranes were characterized using various techniques, including SEM, Raman spectroscopy, XRD, optical profilometer, and FTIR, to confirm their behavior, morphology, and structural integrity. The surface area of ON11 was 423.26 m2 g-1, with BJH average pore diameter of 4.5 nm and BET pore volume of 0.26 cm3 g-1. ON11 nanoparticles were adsorptive in nature, and their utility in membrane adsorption is explored. The influence of parameters, including contact time, dye concentration, membrane thickness, pH, and adsorbent dosage, was systematically evaluated to optimize the dye adsorption efficiency of the ON11@PSU membrane pad. It was observed that the thickness of the 60 μm membrane (S a = 2.170 μm and S q = 2.75 μm) showed higher removal efficiency for all the selected dyes than the other thicknesses at the native pH itself. The MMM demonstrated its effectiveness as an adsorbent membrane, achieving maximum removal efficiencies of approximately 98% for MG dye, 92% for RhB dye, and 67% for MB dye. The negative zeta potential of adsorptive membranes enabled the electrostatic attraction of positively charged dyes, enhancing adsorption capacity. The findings contribute to developing sustainable and effective membrane utility as adsorbents, opening avenues for the effective use of agricultural waste products in environmental remediation applications.

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Novel approach for effective removal of methylene blue dye from water using fava bean peel waste.

Publications

Novel approach for effective removal of methylene blue dye from water using fava bean peel waste.

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