Supply of phosphate to early Earth by photogeochemistry after meteoritic weathering.

ABSTRACT: During terrestrial differentiation, the relatively small amount of phosphorus that migrated to the lithosphere was incorporated into igneous rock, predominantly in the form of basic calcium orthophosphate (Ca₁₀(PO₄)₆(OH,F,Cl)₂, apatite). Yet, the highly insoluble nature of calcium apatite presents a significant problem to those contemplating the origin of life given the foundational role of phosphate (PO₄ ^3-) in extant biology and the apparent requirement for PO₄ ^3- as a catalyst, buffer and reagent in prebiotic chemistry. Reduced meteorites such as enstatite chondrites are highly enriched in phosphide minerals, and upon reaction with water these minerals can release phosphorus species of various oxidat

SUBMITTER: Ritson DJ 

PROVIDER: S-EPMC7213494 | biostudies-literature | 2020 May

REPOSITORIES: biostudies-literature