Coordination Polymers Based on a Biphenyl Tetraphosphonate Linker: Synthesis Control and Photoluminescence.

ABSTRACT: In this work, we used the rigid tetrapodal organic linker, [1,1'-biphenyl]-3,3',5,5'-tetrayltetrakis(phosphonic acid) (H₈btp), for the preparation of two lanthanide-organic framework families of compounds: layered [Ln₇(H₅btp)₄(H_5.5btp)₂(H₆btp)₂(H₂O)₁₂]∙23.5H₂O∙MeOH [where Ln³⁺ = Eu³⁺ (1Eu) and Gd³⁺ (1Gd)], prepared using microwave-irradiation followed by slow evaporation; 3D [Ln₄(H₃btp)(H₄btp)(H₅btp)(H₂O)₈]∙3H₂O [where Ln³⁺ = Ce³⁺ (2Ce), Pr³⁺ (2Pr), and Nd³⁺ (2Nd)], obtained from conve

SUBMITTER: Firmino ADG 

PROVIDER: S-EPMC7221988 | biostudies-literature | 2020 Apr

REPOSITORIES: biostudies-literature