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Synthesis and properties of tetrathiafulvalenes bearing 6-aryl-1,4-dithiafulvenes.
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ABSTRACT:
SUBMITTER: Yoshimura A
PROVIDER: S-EPMC7237811 | biostudies-literature | 2020
REPOSITORIES: biostudies-literature
Publications
Synthesis and properties of tetrathiafulvalenes bearing 6-aryl-1,4-dithiafulvenes.
Beilstein journal of organic chemistry 20200512
Novel multistage redox tetrathiafulvalenes (TTFs) bearing 6-aryl-1,4-dithiafulvene moieties were synthesized by palladium-catalyzed direct C-H arylation. In the presence of a catalytic amount of Pd(OAc)<sub>2</sub>, P(<i>t</i>-Bu<sub>3</sub>)·HBF<sub>4</sub>, and an excess of Cs<sub>2</sub>CO<sub>3</sub>, the C-H arylation of TTF with several aryl bromides bearing 1,3-dithiol-2-ylidenes took place efficiently to produce the corresponding π-conjugated molecules. We also succeeded in the estimatio ...[more]