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CO-Reductive and O₂-Oxidative Annealing Assisted Surface Restructure and Corresponding Formic Acid Oxidation Performance of PdPt and PdRuPt Nanocatalysts.

ABSTRACT: Formic acid oxidation reaction (FAOR) at anode counterpart incurs at substantial high overpotential, limiting the power output efficiency of direct formic acid fuel cells (DFAFCs). Despite intense research, the lack of high-performance nanocatalysts (NCs) for FAOR remains a challenge in realizing DFAFC technologies. To surmount the overpotential losses, it is desirable to have NCs to trigger the FAOR as close to the reversible conditions (i.e. with over-potential loss as close to zero as possible). Herein, Pd-based binary and ternary NCs consisting of PdPt and PdRuPt have been synthesized via the polyol reduction method on the carbon support. As prepared PdPt and PdRuPt NCs were further subjected to heat treatment (annealed) in CO (namely PdPt-CO and PdRuPt-CO) and O₂ (namely Pd

SUBMITTER: Bhalothia D

PROVIDER: S-EPMC7242419 | biostudies-literature | 2020 May

REPOSITORIES: biostudies-literature

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CO-Reductive and O₂-Oxidative Annealing Assisted Surface Restructure and Corresponding Formic Acid Oxidation Performance of PdPt and PdRuPt Nanocatalysts.

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CO-Reductive and O2-Oxidative Annealing Assisted Surface Restructure and Corresponding Formic Acid Oxidation Performance of PdPt and PdRuPt Nanocatalysts.

OmicsDI is part of the ELIXIR infrastructure

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CO-Reductive and O₂-Oxidative Annealing Assisted Surface Restructure and Corresponding Formic Acid Oxidation Performance of PdPt and PdRuPt Nanocatalysts.