Structural Investigations of MA1-xDMAxPbI3 Mixed-Cation Perovskites.

ABSTRACT: Recently, a number of variations to the hybrid perovskite structure have been suggested in order to improve on the properties of methylammonium lead iodide, the archetypical hybrid halide perovskite material. In particular, with respect to the chemical stability of the material, steps should be taken. We performed an in-depth analysis of the structure of MAPbI3 upon incorporation of dimethylammonium (DMA) in order to probe the integrity of the perovskite lattice in relation to changes in the organic cation. This material, with formula MA1-xDMAxPbI3, adopts a 3D perovskite structure for 0 < x < 0.2, while a nonperovskite yellow phase is formed for 0.72 < x < 1. In the perovskite phase, the methylammonium and dimethylammonium ions are distributed randomly throughout the lattice. For 0.05 < x

SUBMITTER: Franssen WMJ 

PROVIDER: S-EPMC7252946 | biostudies-literature | 2020 Mar

REPOSITORIES: biostudies-literature