Measuring Nanoparticle Polarizability Using Fluorescence Microscopy.

ABSTRACT: Using a novel method developed to quantify the polarizability of photoluminescent nanoparticles in water, we present experimental observations of the extraordinary polarizability exhibited by nanoparticles of commensurate size with the Debye screening length, confirming previously reported theory. Semiconductor quantum dots (QDs) are ideal model nanoparticles to demonstrate this assay, due to their tunable size and bright photoluminescence. This assay is based upon microfluidic chambers with microelectrodes that generate trapping potentials that are weaker than thermal energy. By comparing the local electric field strength and variations in QD concentration, their polarizability was computed and found to agree with estimates based upon the hydrodynamic diameter found using light scattering

SUBMITTER: Cao W 

PROVIDER: S-EPMC7271685 | biostudies-literature | 2019 Aug

REPOSITORIES: biostudies-literature