Hydro-thermal synthesis and crystal structure of poly[bis-(μ₃-3,4-di-amino-benzoato)manganese], a layered coordination polymer.

ABSTRACT: The hydro-thermal synthesis and crystal structure of the title two-dimensional coordination polymer, poly[bis-(μ₃-3,4-di-amino-benzoato-κ³ N ³,O,O')manganese(II)], [Mn(C₇H₇N₂O₂)₂] _n , are described. The Mn²⁺ cation (site symmetry ) adopts a tetra-gonally elongated trans-MnN₂O₄ octa-hedral coordination geometry and the μ³-N,O,O' ligand (bonding from both carboxyl-ate O atoms and the meta-N atom) links the metal ions into infinite (10) layers. The packing is consolidated by intra-layer N-H⋯O and inter-layer N-H⋯N hydrogen bonds. The structure of the title compound is compared with other co

SUBMITTER: Khosa MK 

PROVIDER: S-EPMC7273982 | biostudies-literature | 2020 Jun

REPOSITORIES: biostudies-literature