Synthesis and crystal structure of two manganese-based 12-metallacrown-4 complexes: Na<sub>2</sub>(3-chloro-benzoate)<sub>2</sub>[12-MC<sub>Mn(III)N(shi)</sub>-4](DMF)<sub>6</sub> and MnNa(3-chloro-benzoate)<sub>3</sub>[12-MC<sub>Mn(III)N(shi)</sub>-4](DMF)(H<sub>2</sub>O)<sub>4</sub>·4DMF·0.72H<sub>2</sub>O.
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ABSTRACT: Similar synthetic schemes yield two different metallacrown (MC) complexes: bis-(μ-3-chloro-benzoato)hexa-kis-(di-methyl-formamide)-tetra-kis-(μ4-N,2-dioxido-benzene-1-carboximidato)tetra-manganese(III)disodium(I), [Mn4Na2(C7H4ClO2)2(C7H4NO3)4(C3H7NO)6] or Na2(3-chloro-benzoate)2[12-MCMn(III)N(shi)-4](DMF)6, 1, and tetra-μ-aqua-tris-(μ-3-chloro-benzoato)(di-methyl-formamide)-tetra-kis-(μ4-N,2-dioxido-benzene-1-carboximidato)penta-manganese(III)sodi-um(I) di-methyl-formamide tetra-solvate 0.72-hydrate, [Mn5Na(C7H4ClO2)
SUBMITTER: Zaleski CM
PROVIDER: S-EPMC7274016 | biostudies-literature | 2020 Jun
REPOSITORIES: biostudies-literature
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