O-coordinated W-Mo dual-atom catalyst for pH-universal electrocatalytic hydrogen evolution.

ABSTRACT: Single-atom catalysts (SACs) maximize the utility efficiency of metal atoms and offer great potential for hydrogen evolution reaction (HER). Bimetal atom catalysts are an appealing strategy in virtue of the synergistic interaction of neighboring metal atoms, which can further improve the intrinsic HER activity beyond SACs. However, the rational design of these systems remains conceptually challenging and requires in-depth research both experimentally and theoretically. Here, we develop a dual-atom catalyst (DAC) consisting of O-coordinated W-Mo heterodimer embedded in N-doped graphene (W₁Mo₁-NG), which is synthesized by controllable self-assembly and nitridation processes. In W₁Mo₁-NG, the O-bridged W-Mo atoms are anchored in NG vacancies through

SUBMITTER: Yang Y 

PROVIDER: S-EPMC7274769 | biostudies-literature | 2020 Jun

REPOSITORIES: biostudies-literature