A Hybrid {Silk@Zirconium MOF} Material as Highly Efficient As^III-sponge.

ABSTRACT: Exposure of humans to Arsenic from groundwater drinking sources is an acute global public health problem, entailing the urgent need for highly efficient/low-cost Arsenite (As^III) up-taking materials. Herein we present an innovative hybrid-material, ZrMOF@SF_d operating like an "As^III-sponge" with unprecedented efficiency of 1800 mg As^III gr^-1. ZrMOF@SF_d consists of a neutral Zirconium Metal-Organic Framework [ZrMOF] covalently grafted on a natural silk-fiber (SF_d). ZrMOF itself exhibits As^III adsorption of 2200 mg gr^-1, which supersedes any -so far- known As^ΙΙΙ-sorbent. Using XPS, FTIR, BET-porosimetry data, together with theoretical Surface-Complexation-Modeling (SCM), we show that

SUBMITTER: Georgiou Y 

PROVIDER: S-EPMC7283345 | biostudies-literature | 2020 Jun

REPOSITORIES: biostudies-literature