Cu(II)-Hydrazide Coordination Compound Supported on Silica Gel as an Efficient and Recyclable Heterogeneous Catalyst for Green Click Synthesis of β-Hydroxy-1,2,3-triazoles in Water.

ABSTRACT: A hydrazone ligand, (E)-6-(2-((2-hydroxynaphthalen-1-yl)methylene)hydrazinyl)nicotinohydrazide (H₂L), was synthesized and characterized by spectroscopic methods. The reaction of H₂L with CuCl₂·2H₂O in methanol gave Cu(II) coordination compound, [Cu(HL')(Cl)]·CH₃OH (1), which was characterized by elemental analysis and spectroscopic methods (Fourier transform infrared (FT-IR) and UV-vis). The structure of 1 was also determined by single-crystal X-ray analysis. Structural studies confirmed the formation of esteric group during the synthesis of 1. Compound 1 was immobilized on 3-aminopropyltriethoxysilane (APTS)-functionalized silica gel through the amidification reaction and the obtained heterogeneous c

SUBMITTER: Emami M 

PROVIDER: S-EPMC7288712 | biostudies-literature | 2020 Jun

REPOSITORIES: biostudies-literature