An S₁₀-Symmetric 5-Fold Interlocked [2]Catenane.

ABSTRACT: The reaction of sym-pentakis(4-aminothiophenyl)corannulene with 2-formyl-6-methylpyridine and Cu^I or 2-formyl-1,10-phenanthroline and M^II (M = Co, Zn) yields an S₁₀-symmetric 5-fold interlocked [2]catenane of two interpenetrating [Cu^I₅L₂]⁵⁺ cages or D₅-symmetric [M^II₅L₂]¹⁰⁺ cages, respectively. The new structures were characterized by X-ray crystallography, NMR spectroscopy, and mass spectrometry. Density functional theory computations point to dispersive energies on par with traditional covalent bond energies. Subcomponent exchange reactions favored formation of the [Co^II₅L₂]¹⁰⁺ cage over the [C

SUBMITTER: Ronson TK 

PROVIDER: S-EPMC7291353 | biostudies-literature | 2020 Jun

REPOSITORIES: biostudies-literature