Metal-Organic Frameworks with Hexakis(4-carboxyphenyl)benzene: Extensions to Reticular Chemistry and Introducing Foldable Nets.

ABSTRACT: Nine metal-organic frameworks have been prepared with the hexagon-shaped linker 1,2,3,4,5,6-hexakis(4-carboxyphenyl)benzene (H₆cpb) by solvothermal reactions in dimethylformamide (dmf) or dimethylacetamide (dmac) with acetic acid or formic acid as modulators: [Bi₂(cpb)(acetato)₂(dmf)₂]·2dmf CTH-6 forms a rtl-net; 2(H₂NMe₂)[Cu₂(cpb)] CTH-7 forms a kgd-net; [Fe₄(cpb)(acetato)₂(dmf)₄] CTH-8 and [Co₄(cpb)(acetato)₂(dmf)₄] CTH-9 are isostructural and form yav-nets; 2(HNEt₃)[Fe₂(cpb)] CTH-10 and the two polymorphs of 2(H₂NMe₂)[Zn₂(cpb)]·1.5dmac,

SUBMITTER: Amombo Noa FM 

PROVIDER: S-EPMC7304877 | biostudies-literature | 2020 May

REPOSITORIES: biostudies-literature