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Adsorption of Fatty Acid Molecules on Amine-Functionalized Silica Nanoparticles: Surface Organization and Foam Stability.


ABSTRACT: The crucial roles of the ionization state and counterion presence on the phase behavior of fatty acid in aqueous solutions are well-established. However, the effects of counterions on the adsorption and morphological state of fatty acid on nanoparticle surfaces are largely unknown. This knowledge gap exists due to the high complexity of the interactions between nanoparticles, counterions, and fatty acid molecules in aqueous solution. In this study, we use adsorption isotherms, small angle neutron scattering, and all-atom molecular dynamic simulations to investigate the effect of addition of ethanolamine as a counterion on the adsorption and self-assembly of decanoic acid onto aminopropyl-modified silica nanoparticles. We show that the morphology of the fatty acid assemblies on silica nanop

SUBMITTER: Ma Y 

PROVIDER: S-EPMC7311077 | biostudies-literature | 2020 Apr

REPOSITORIES: biostudies-literature