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Synergism of Multicomponent Catalysis: One-Dimensional Pt-Rh-Pd Nanochain Catalysts for Efficient Methanol Oxidation.


ABSTRACT: Designing Pt-based alloy catalysts with multicomponent composition and a controllable structure is important to improve the utilization efficiency of precious metals and catalytic activity, but it still face a lot of challenges for simple preparation. Herein, we used insulin amyloid fibrils as templates and their own one-dimensional spiral structure to synthesize Pt-Rh-Pd ternary alloy nanochains under mild conditions. The prepared Pt-Rh-Pd alloy nanochains (NCs) have uniform diameter, and the particle size is only 2 nm. This ultrafine structure increases the specific surface area of the catalyst to a certain extent, and the synergistic effect of the three metals improves the catalytic performance. Compared with commercial Pt/C and binary Pt-Rh NCs, the as-presented Pt-Rh-Pd NCs show bette

SUBMITTER: Jiang Y 

PROVIDER: S-EPMC7315591 | biostudies-literature | 2020 Jun

REPOSITORIES: biostudies-literature