Supramolecular Polymer Brushes: Influence of Molecular Weight and Cross-Linking on Linear Viscoelastic Behavior.

ABSTRACT: The origin of unique rheological response in supramolecular brush polymers is investigated using different polymer chemistries (poly(methyl acrylate) (PmA) and poly(ethylene glycol) (PEG)), topologies (linear or star), and molecular weights. A recently developed hydrogen-bonding moiety (1-(6-isocyanatohexyl)-3-(7-oxo-7,8-dihydro-1,8-naphthyridin-2-yl)-urea) (ODIN) was coupled to PmAs and PEGs to form supramolecular brush polymers, the backbone of which is formed by the associated moieties. At low molecular weights of monofunctionalized polymers (both PmA and PEG), the formed brushes are mostly composed of a thick backbone (with very short arms) and are surrounded by other similar brush polymers, which prevent them from diffusing and relaxing. Therefore, the monofunctionalized PmA with a lo

SUBMITTER: Golkaram M 

PROVIDER: S-EPMC7315638 | biostudies-literature | 2020 Jun

REPOSITORIES: biostudies-literature