Self-Assembly of Aminocyclopropenium Salts: En Route to Deltic Ionic Liquid Crystals.

ABSTRACT: Aminocyclopropenium ions have raised much attention as organocatalysts and redox active polymers. However, the self-assembly of amphiphilic aminocyclopropenium ions remains challenging. The first deltic ionic liquid crystals based on aminocyclopropenium ions have been developed. Differential scanning calorimetry, polarizing optical microscopy and X-ray diffraction provided insight into the unique self-assembly and nanosegregation of these liquid crystals. While the combination of small headgroups with linear p-alkoxyphenyl units led to bilayer-type smectic mesophases, wedge-shaped units resulted in columnar mesophases. Upon increasing the size and polyphilicity of the aminocyclopropenium headgroup, a lamellar phase was formed.

SUBMITTER: Litterscheidt J 

PROVIDER: S-EPMC7317216 | biostudies-literature | 2020 Jun

REPOSITORIES: biostudies-literature